Nano-rod solar cell generates hydrogen

A new type of solar collector that uses gold nano-rods could convert sunlight into energy without many of the problems associated with traditional photovoltaic solar cells.

The developers of the new technique, from the University of California – Santa Barbara, say it is “the first radically new and potentially workable alternative to semiconductor-based photovoltaic devices to be developed in the past 70 years.” They provide details of the new solar hydrogen generator in the journal Nature Nanotechnology.

In conventional photovoltaic cells, sunlight hits the surface of semiconductor material, one side of which is electron-rich, while the other side is not. The photon excites the electrons, causing them to leave their positions, and create positively-charged “holes.” The result is a current of charged particles – electricity.

In the new technique, it is not semiconductor materials that provide the electrons and venue for the conversion of solar energy, but a “forest” of gold nano-rods operating in water. Specifically, gold nano-rods capped with a layer of crystalline titanium dioxide and platinum, and a cobalt-based oxidation catalyst deposited on the lower portion of the array.

“When nanostructures, such as nano-rods, of certain metals are exposed to visible light, the conduction electrons of the metal can be caused to oscillate collectively, absorbing a great deal of the light,” explained Martin Moskovits (pictured front center), a professor of chemistry at UCSB. “This excitation is called a surface plasmon.”

As the “hot” electrons in these plasmonic waves are excited by light particles, some travel up the nano-rod, through a filter layer of crystalline titanium dioxide, and are captured by platinum particles. This causes the reaction that splits hydrogen ions from the bond that forms water. Meanwhile, the holes left behind by the excited electrons head toward the cobalt-based catalyst on the lower part of the rod to form oxygen.

The researchers say that hydrogen production was clearly observable after about two hours. Importantly, the nano-rods were not subject to the photo-corrosion that often causes traditional semiconductor materials to fail and Moskovits says the device operated with no hint of failure for “many weeks.”

Though still in its infancy, the research promises a more robust method of converting sunlight into energy. “Despite the recentness of the discovery, we have already attained ‘respectable’ efficiencies. More importantly, we can imagine achievable strategies for improving the efficiencies radically,” Moskovits said.

Related:
Discuss this article in our forum
Stanford announces peel-and-stick solar panels
Solar steam generator outshines photovoltaic solar cells
Solar power’s dirty secret: skyrocketing lead pollution
Much simpler catalyst could fast-track hydrogen economy

Source: University of California – Santa Barbara

, ,

Comments are closed.

Solar Plane Air Freshener Airplane Aromatherapy Diffuser Ornament picture

Solar Plane Air Freshener Airplane Aromatherapy Diffuser Ornament

$15.00



Solar Powered Inspired on No Face, Spirited Away Dancing Anime Bobble Head Decor picture

Solar Powered Inspired on No Face, Spirited Away Dancing Anime Bobble Head Decor

$14.94



Solar Lighted Virgin Mary Blessed Mother Garden Lawn Statue Sculpture 11''H picture

Solar Lighted Virgin Mary Blessed Mother Garden Lawn Statue Sculpture 11''H

$49.36



Solar Flare Wonderstone Slab ,315 Gram, 7”x5”x5/16” XL, Beautiful picture

Solar Flare Wonderstone Slab ,315 Gram, 7”x5”x5/16” XL, Beautiful

$24.99



Your Name Message Solar Power Blinking Key Chain Ring Keychain No need battery picture

Your Name Message Solar Power Blinking Key Chain Ring Keychain No need battery

$4.99



Solar Man of the Atom 10 First Printing Valiant 1992 picture

Solar Man of the Atom 10 First Printing Valiant 1992

$25.00



Pink Hello Kitty Moving Head Solar Car Decoration picture

Pink Hello Kitty Moving Head Solar Car Decoration

$13.75



Charity Sale- Solar Portable Buddhist Chanting Machine 4 x 2.5 x 0.75 in picture

Charity Sale- Solar Portable Buddhist Chanting Machine 4 x 2.5 x 0.75 in

$10.00



Solar Man Of The Atom #10, 11, 14, 28 - 1992 1993 (HM518) Valiant picture

Solar Man Of The Atom #10, 11, 14, 28 - 1992 1993 (HM518) Valiant

$9.99



Gothic Crouching Winged Gargoyle Statue With Solar LED Lantern Light Post 20

Gothic Crouching Winged Gargoyle Statue With Solar LED Lantern Light Post 20"H

$79.95



Powered by WordPress. Designed by WooThemes