The search for methane in Earth's mantle'The idea that methane could be formed nonbiogenically came from observing the solar system'
U.S. Department of Energy
Petroleum geologists have long searched beneath Earth's surface for oil and gas, knowing that hydrocarbons form from the decomposition of plants and animals buried over time. However, methane, the most plentiful hydrocarbon in Earth's crust, is also found where biological deposits seem inadequate or improbable?for example, in great ocean rifts, in igneous and metamorphic rocks, and around active volcanoes. Some scientists thus wonder whether untapped reserves of natural gas may exist in Earth's mantle.
A collaboration of researchers from Lawrence Livermore and Argonne national laboratories, Carnegie Institution's Geophysical Laboratory, Harvard University, and Indiana University at South Bend is finding that methane may also be formed from nonbiological processes. Experiments and calculations conducted by the team indicate that Earth's mantle may provide the temperature and pressure conditions necessary to produce methane.
http://www.eurekalert.org/features/doe/2005-08/drnl-tsf082205.php